Impact of functional group types in ion exchange resins on rare earth element recovery from treated acid mine waters
نویسندگان
چکیده
Ion-exchange (IX) resins incorporating single functional groups (sulfonic or amino-phosphonic) and two phosphonic) were evaluated for selective recovery of Rare Earth Elements (REEs) from acidic mine waters (AMW). The composition AMW solution, complexing properties the group, acidity investigated as key parameters concentration separation REEs transition elements (TEs). Fe has to be removed enable REE here was treated with NaOH solutions reach pH 3.9 where Fe(III) selectively (?99%) by precipitation schwertmannite. Single IX resin containing a sulfonic group displayed higher efficiency ratio than observed bi-functional (sulfonic/phosphonic). Concentration factors between 30 40 achieved using regeneration cycles H2SO4. performance aminophosphonic showed lower TEs groups. improved tuning match reactivity, adjustment range 0.5–2.0 provided highest REE/TE factor followed bifunctional resin. integration an elution cycle Na2-EDTA/NH4Cl mixtures strongly increases Light (LREE) up 260
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ژورنال
عنوان ژورنال: Journal of Cleaner Production
سال: 2022
ISSN: ['0959-6526', '1879-1786']
DOI: https://doi.org/10.1016/j.jclepro.2022.134742